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Torsten Roth Vladislav Vasilenko Callum G. M. Benson Hubert Wadepohl Dominic S. Wright Lutz H. Gade 《Chemical science》2015,6(4):2506-2510
A simple, “click” synthetic approach to a new type of hybrid phosph(III)azane/NHC system is described. The presence of the phosphazane P2N2 ring unit, with P atoms flanking the NCN fragment and with this ring perpendicular to the binding site of the NHC, provides unique opportunities for modifying the electronic and steric character of these carbenes. 相似文献
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An arc of a digraph is called universal if and are in a common cycle for any vertex of . In this paper we characterize local tournaments whose every arc is universal. 相似文献
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Robbert van Putten Evgeny A. Uslamin Marcel Garbe Chong Liu Dr. Angela Gonzalez-de-Castro Dr. Martin Lutz Dr. Kathrin Junge Prof. Dr. Emiel J. M. Hensen Prof. Dr. Matthias Beller Dr. Laurent Lefort Prof. Dr. Evgeny A. Pidko 《Angewandte Chemie (International ed. in English)》2017,56(26):7531-7534
Catalytic hydrogenation of carboxylic acid esters is essential for the green production of pharmaceuticals, fragrances, and fine chemicals. Herein, we report the efficient hydrogenation of esters with manganese catalysts based on simple bidentate aminophosphine ligands. Monoligated Mn PN complexes are particularly active for the conversion of esters into the corresponding alcohols at Mn concentrations as low as 0.2 mol % in the presence of sub-stoichiometric amounts of KOtBu base. 相似文献
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Robert Eichelmann Dr. Joachim Ballmann Prof. Lutz H. Gade 《Angewandte Chemie (International ed. in English)》2023,62(35):e202309198
Tetraazacoronenes were synthesized from bay-functionalized tetraazaperylenes by Zr-mediated cyclization and four-fold Suzuki–Miyaura cross coupling. In the Zr-mediated approach, an η4-cyclobutadiene-zirconium(IV) complex was isolated as an intermediate to cyclobutene-annulated derivatives. Using bis(pinacolatoboryl)vinyltrimethylsilane as a C2 building block gave the tetraazacoronene target compound along with the condensed azacoronene dimer as well as higher oligomers. The series of extended azacoronenes show highly resolved UV/Vis absorption bands with increased extinction coefficients for the extended aromatic cores and fluorescence quantum yields of up to 80 % at 659 nm. 相似文献
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Emily C. Monkcom Daniël de Bruin Annemiek J. de Vries Dr. Martin Lutz Dr. Shengfa Ye Prof. Dr. Robertus J. M. Klein Gebbink 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(16):5191-5204
We present the synthesis and coordination chemistry of a bulky, tripodal N,N,O ligand, ImPh2NNO t Bu ( L ), designed to model the 2-His-1-carboxylate facial triad (2H1C) by means of two imidazole groups and an anionic 2,4-di-tert-butyl-subtituted phenolate. Reacting K-L with MCl2 (M = Fe, Zn) affords the isostructural, tetrahedral non-heme complexes [Fe(L)(Cl)] ( 1 ) and [Zn(L)(Cl)] ( 2 ) in high yield. The tridentate N,N,O ligand coordination observed in their X-ray crystal structures remains intact and well-defined in MeCN and CH2Cl2 solution. Reacting 2 with NaSPh affords a tetrahedral zinc thiolate complex, [Zn(L)(SPh)] ( 4 ), that is relevant to isopenicillin N synthase (IPNS) biomimicry. Cyclic voltammetry studies demonstrate the ligand's redox non-innocence, where phenolate oxidation is the first electrochemical response observed in K-L , 2 and 4 . However, the first electrochemical oxidation in 1 is iron-centred, the assignment of which is supported by DFT calculations. Overall, ImPh2NNO t Bu provides access to well-defined mononuclear, monoligated, N,N,O-bound metal complexes, enabling more accurate structural modelling of the 2H1C to be achieved. 相似文献